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Title: Determination of D[(C2H5)3Sn-C2H5] by the toluene carrier method and studies of the reaction of C2H5 with toluene
Journal: Can. J. Chem.
Volume: 54
Page(s): 1814 - 1819
Year: 1976
Reference type: Journal article
Squib: 1976DAL/PRI1814-1819
Reaction:
Toluene + ·C2H5 → C2H6 + Benzyl
Reaction order:
2
Temperature:
725 - 833
K
Pressure: 7.31E-3 - 8.71E-3 bar
Rate expression:
3.17x10-13 [cm3/molecule s] e-43069 [±3875 J/mole]/RT
Bath gas:
N2
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 725 | 2.50E-16 |
| 750 | 3.18E-16 |
| 775 | 3.97E-16 |
| 800 | 4.89E-16 |
| 825 | 5.95E-16 |
| 833 | 6.32E-16 |