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Accessibility information
Author(s):   Davis, D.D.; Machado, G.; Conaway, B.; Oh, Y.; Watson, R.
Title:   A temperature dependent kinetics study of the reaction of OH with CH3Cl, CH2Cl2, CHCl3, and CH3Br
Journal:   J. Chem. Phys.
Volume:   65
Page(s):  
Year:   1976
Reference type:   Journal article
Squib:   1976DAV/MAC1268

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1976DAV/MAC1268   CHCl3 + ·OH → ·CCl3 + H2O  245 - 375   4.68E-12       9395   1.06E-13  2
  1976DAV/MAC1268   CH3Br + ·OH → H2O + ·CH2Br  245 - 375   7.95E-13       7383   4.04E-14  2
  1976DAV/MAC1268   CH3Cl + ·OH → ·CH2Cl + H2O  245 - 375   1.84E-12       9146   4.60E-14  2
  1976DAV/MAC1268   CH2Cl2 + ·OH → CHCl2 + H2O  245 - 375   4.27E-12       9063   1.10E-13  2
Search returned 4 records.