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Accessibility information
Author(s):   Gaynor, B.J.; Gilbert, R.G.; King, K.D.; Mackie, J.C.
Title:   The isomerization of cycloheptatriene at high temperatures
Journal:   Int. J. Chem. Kinet.
Volume:   8
Page(s):  
Year:   1976
Reference type:   Journal article
Squib:   1976GAY/GIL695

Reaction:   1,3,5-CycloheptatrieneToluene
Reaction order:   1
Temperature:   800 - 1130 K
Rate expression:   3.98x1013 [s-1] e-217839 [±2178 J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
800 2.38E-1
825 6.42E-1
850 1.63E0
875 3.94E0
900 9.06E0
925 1.99E1
950 4.19E1
975 8.50E1
1000 1.66E2
1025 3.15E2
1050 5.80E2
1075 1.04E3
1100 1.80E3
1125 3.06E3
1130 3.39E3