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Title: Study of the Spectra and Recombination Kinetics of Alkyl Radicals by Molecular Modulation Spectrometry. Part 2. The Recombination of Ethyl, Isopropyl and t-Butyl Radicals at Room Temperature and t-Butyl Radicals between 250 and 450 K
Journal: J. Chem. Soc. Faraday Trans. 1
Volume: 72
Page(s):
Year: 1976
Reference type: Journal article
Squib: 1976PAR/QUI1952
Reaction:
·C2H5 + ·C2H5 → n-C4H10
Reaction order:
2
Reference reaction:
·C2H5 + ·C2H5 → C2H6 + C2H4
Temperature:
298
K
Pressure: 1.01 bar
Rate expression:
1.3x10-11 [±2.99x10-12 cm3/molecule s]
Bath gas:
N2
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Direct photolysis
Analytical technique:
Vis-UV absorption
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