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Title: Pyrolysis of t-butyl N-arylcarbamates in the gas phase, and correlation of the elimination rates with those obtained in solution
Journal: J. Chem. Soc. Perkin Trans. 2
Page(s): 799 - 802
Year: 1976
Reference type: Journal article
Squib: 1976TAY/THO799-802
Reaction:
Carbamic acid, (4-methylphenyl)-, 1,1-dimethylethyl ester → 4-Methylbenzenamine + iso-C4H8 + CO2
Reaction order:
1
Temperature:
548
K
Rate expression:
1.15x10-2 [s-1]
Bath gas:
Chlorobenzene
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Other (direct)
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