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Title: The chlorination of paraffin hydrocarbons. Calculation of the activation energies and A factors for reactions in the total chlorination of methane
Journal: J. Phys. Chem.
Volume: 81
Page(s): 2610 - 2614
Year: 1977
Reference type: Journal article
Squib: 1977BEL/PER2610-2614
Reaction:
CHCl3 + Cl → CHCl2 + Cl2
Reaction order:
2
Temperature:
350 - 450
K
Rate expression:
3.32x10-11 [cm3/molecule s] e-111414 [J/mole]/RT
Category: Theory
Data type:
Bond energy-bond order (BEBO)
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 350 | 7.83E-28 |
| 375 | 1.01E-26 |
| 400 | 9.38E-26 |
| 425 | 6.73E-25 |
| 450 | 3.88E-24 |