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Title: Studies in Decarboxylation. Part 10. Effect of β-Substituents on the Rate of Gas-phase Decarboxylation of ββββπβ-Unsaturated Acids
Journal: J. Chem. Soc. Perkin Trans. 2
Page(s):
Year: 1977
Reference type: Journal article
Squib: 1977BIG/WEA745
Reaction:
CH2=C(CH3)C(CH3)2COOH → CO2 + (CH3)2C=C(CH3)2
Reaction order:
1
Temperature:
500
K
Pressure: 6.67E-2 - 0.67 bar
Rate expression:
2.94x10-4 [s-1]
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Mass spectrometry
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