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Author(s):   Bonanno, R.J.; Timmons, R.B.; Stief, L.J.; Klemm, R.B.
Title:   The Kinetics and Mechanisms of the Reactions of O(3P) Atoms with CH3CN and CF3CN
Journal:   J. Chem. Phys.
Volume:   66
Year:   1977
Reference type:   Journal article
Squib:   1977BON/TIM92

Reaction:   CH3CN + → Products
Reaction order:   2
Reference reaction:   CD3CN + → Products
Reference reaction order:   2
Temperature:   383 - 423 K
Pressure:  0.13 - 0.40 bar
Rate expression:   1.27x101 e-7516 [J/mole]/RT
Uncertainty:   2.0899999
Bath gas:   Ar
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Resonance fluorescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
383 1.20E0
400 1.33E0
423 1.50E0