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Title: The Kinetics and Mechanisms of the Reactions of O(3P) Atoms with CH3CN and CF3CN
Journal: J. Chem. Phys.
Volume: 66
Page(s):
Year: 1977
Reference type: Journal article
Squib: 1977BON/TIM92
Reaction:
CH3CN + O· → Products
Reaction order:
2
Reference reaction:
CD3CN + O· → Products
Reference reaction order:
2
Temperature:
383 - 423
K
Pressure: 0.13 - 0.40 bar
Rate expression:
1.27x101 e-7516 [J/mole]/RT
Uncertainty:
2.0899999
Bath gas:
Ar
Category: Experiment
Data type:
Relative rate value measured
Excitation technique:
Flash photolysis (laser or conventional)
Analytical technique:
Resonance fluorescence
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [] |
|---|---|
| 383 | 1.20E0 |
| 400 | 1.33E0 |
| 423 | 1.50E0 |