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Title: Reactions of Oxygenated Radicals in the Gas Phase. Part 3. Reactions of Peracetyl Radicals with Alkenes
Journal: J. Chem. Soc. Perkin Trans. 2
Volume: 3
Page(s):
Year: 1977
Reference type: Journal article
Squib: 1977DIA/SEL360
Reaction:
(CH3)2CHCH=CH2 + CH3C(O)OO(·) → CO2 + Oxirane,(1-methylethyl)- + ·CH3
Reaction order:
2
Temperature:
393
K
Pressure: 0.28 bar
Rate expression:
2.08x10-17 [±1.05x10-17 cm3/molecule s]
Bath gas:
O2
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
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