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Title: Kinetics od thw Gas-Phase Decomposition of 1,2-Epoxypropane
Journal: J. Chem. Soc. Faraday Trans. 1
Volume: 73
Page(s):
Year: 1977
Reference type: Journal article
Squib: 1977FLO1927
Reaction:
Methyloxirane → CH2=CHCH2OH
Reaction order:
1
Temperature:
654 - 717
K
Pressure: 6.67E-3 - 0.43 bar
Rate expression:
7.94x1012 [s-1] e-239457 [±2395 J/mole]/RT
Uncertainty:
1.41
Bath gas:
Methyloxirane
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 654 | 5.96E-7 |
| 675 | 2.34E-6 |
| 700 | 1.08E-5 |
| 717 | 2.85E-5 |