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Accessibility information
Author(s):   Hautecloque, S.
Title:   Reactions des radicaux CH3 avec les molecules CCl4, CFCl3 et CF2Cl2
Journal:   J. Photochem.
Volume:   7
Year:   1977
Reference type:   Journal article
Squib:   1977HAU83

Reaction:   CF2Cl2 + ·CH3CH3Cl + ·CClF2
Reaction order:   2
Reference reaction:   CCl4 + ·CH3CH3Cl + ·CCl3
Temperature:   293 - 411 K
Rate expression:   2.09x10-12 [cm3/molecule s] e-26357 [J/mole]/RT
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
293 4.19E-17
300 5.39E-17
325 1.22E-16
350 2.44E-16
375 4.46E-16
400 7.57E-16
411 9.35E-16