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Author(s):   Huybrechts, G.; Luyckx, L.; Vandenboom, Th.; Van Mele, B.
Title:   Thermal Dimerization of 1,3-Butadiene: Kinetics of the Formation of cis, cis-Cycloocta-1,5-diene
Journal:   Int. J. Chem. Kinet.
Volume:   9
Year:   1977
Reference type:   Journal article
Squib:   1977HUY/LUY283

Reaction:   4-Vinylcyclohexene1,3-Butadiene + 1,3-Butadiene
Reaction order:   1
Temperature:   464 - 557 K
Pressure:  6.53E-2 - 0.60 bar
Rate expression:   2.51x1014 [s-1] e-251929 [±2519 J/mole]/RT
Uncertainty:   3.1600001
Category:  Experiment
Data type:   Derived from detailed balance/reverse rate

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
464 1.10E-14
475 4.97E-14
500 1.21E-12
525 2.16E-11
550 2.98E-10
557 5.95E-10