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Accessibility information
Author(s):   Ormson, B.N.; Perrymore, W.D.; White, M.L.
Title:   Hydrogen abstraction from trichlorosilane by the trichloromethyl and 1,1-dichlorotrifluoroethyl radicals
Journal:   Int. J. Chem. Kinet.
Volume:   9
Year:   1977
Reference type:   Journal article
Squib:   1977ORM/PER663

Reaction:   ·CCl3 + SiHCl3CHCl3 + SiCl3
Reaction order:   2
Temperature:   395 - 476 K
Rate expression:   1.91x10-13 [cm3/molecule s] e-36667 [J/mole]/RT
Bath gas:   CCl4
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
395 2.71E-18
400 3.11E-18
425 5.95E-18
450 1.06E-17
475 1.77E-17
476 1.81E-17