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Accessibility information
Author(s):   Zabel, V.F.
Title:   Der Thermische Zerfall von Chlorierten Athylenen in der Gasphase I. Tetrachloroathylen und Trichloroathylen
Journal:   Ber. Bunsenges. Phys. Chem.
Page(s):   232 - 240
Year:   1977
Reference type:   Journal article
Squib:   1977ZAB232-240

Reaction:   C2Cl4 → Products
Reaction order:   1
Temperature:   1450 - 1900 K
Pressure:  2.03 - 177 bar
Rate expression:   4.5x1014 [s-1] e-334720 [J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   Rate constant is high pressure limit
Experimental procedure:   Other
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   Vis-UV absorption
Comments:   Shock tube measurement.

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1450 3.94E2
1475 6.31E2
1500 9.94E2
1525 1.54E3
1550 2.36E3
1575 3.57E3
1600 5.32E3
1625 7.84E3
1650 1.14E4
1675 1.64E4
1700 2.34E4
1725 3.29E4
1750 4.60E4
1775 6.36E4
1800 8.71E4
1825 1.18E5
1850 1.59E5
1875 2.13E5
1900 2.83E5