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Accessibility information
Author(s):   Amin, H.B.; Taylor, R.
Title:   The mechanism of the gas-phase pyrolysis of esters. Part 6. Pyrolysis of 1-arylethyl benzoates and t-butyl phenylacetates
Journal:   J. Chem. Soc. Perkin Trans. 2
Page(s):  
Year:   1978
Reference type:   Journal article
Squib:   1978AMI/TAY1095

Reaction:   Benzeneacetic acid, 3-chloro-, 1,1-dimethylethyl ester → iso-C4H8 + m-chlorophenylacetic acid
Reaction order:   1
Temperature:   543 - 601 K
Rate expression:   9.12x1012 [s-1] e-161301 [J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Other (direct)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
543 2.78E-3
550 4.38E-3
575 2.03E-2
600 8.28E-2
601 8.73E-2