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Title: Absolute Rate Constant, Kinetic Isotope Effect, and Mechanism of the Reaction of Ethylene Oxide with Oxygen(3P) Atoms
Journal: J. Phys. Chem.
Volume: 82
Page(s):
Year: 1978
Reference type: Journal article
Squib: 1978BOG/HAN2067
Reaction:
Oxirane + O· → ·OH + Oxiranyl
Reaction order:
2
Reference reaction:
Oxirane-d4 + O· → Other Products + OD
Reference reaction order:
2
Temperature:
482 - 691
K
Pressure: 1.33E-3 - 1.19E-2 bar
Rate expression:
8.99x10-1±2.0x10-1 e-6111 [±981 J/mole]/RT
Bath gas:
N2
Category: Experiment
Data type:
Relative rate value measured
Excitation technique:
Electron beam
Analytical technique:
Mass spectrometry
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [] |
|---|---|
| 482 | 1.96E-1 |
| 500 | 2.07E-1 |
| 525 | 2.22E-1 |
| 550 | 2.36E-1 |
| 575 | 2.50E-1 |
| 600 | 2.64E-1 |
| 625 | 2.77E-1 |
| 650 | 2.90E-1 |
| 675 | 3.03E-1 |
| 691 | 3.10E-1 |