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Author(s):   Bogan, D.J.; Hand, C.W.
Title:   Absolute Rate Constant, Kinetic Isotope Effect, and Mechanism of the Reaction of Ethylene Oxide with Oxygen(3P) Atoms
Journal:   J. Phys. Chem.
Volume:   82
Year:   1978
Reference type:   Journal article
Squib:   1978BOG/HAN2067

Reaction:   Oxirane + ·OH + Oxiranyl
Reaction order:   2
Reference reaction:   Oxirane-d4 + → Other Products + OD
Reference reaction order:   2
Temperature:   482 - 691 K
Pressure:  1.33E-3 - 1.19E-2 bar
Rate expression:   8.99x10-1±2.0x10-1 e-6111 [±981 J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Electron beam
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
482 1.96E-1
500 2.07E-1
525 2.22E-1
550 2.36E-1
575 2.50E-1
600 2.64E-1
625 2.77E-1
650 2.90E-1
675 3.03E-1
691 3.10E-1