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Accessibility information
Author(s):   King, K.D.
Title:   Very low-pressure pyrolysis (VLPP) of 3-chloropropionitrile
Journal:   J. Chem. Soc. Faraday Trans. 1
Volume:   74
Page(s):   912 - 918
Year:   1978
Reference type:   Journal article
Squib:   1978KIN912-918

Reaction:   CH2ClCH2CNCH2CHCN + HCl
Reaction order:   1
Temperature:   942 - 1150 K
Rate expression:   1.58x1013 [s-1] e-241120 [±4822 J/mole]/RT
Uncertainty:   2.0
Bath gas:   Ar
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
942 6.74E-1
950 8.73E-1
975 1.91E0
1000 4.02E0
1025 8.15E0
1050 1.60E1
1075 3.04E1
1100 5.61E1
1125 1.01E2
1150 1.77E2