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Accessibility information
Author(s):   Tsang, W.
Title:   Evidence for Strongly Temperature-Dependent A Factors in Alkane Decomposition and High Heats of Formation for Alkyl Radicals
Journal:   Int. J. Chem. Kinet.
Volume:   10
Page(s):  
Year:   1978
Reference type:   Journal article
Squib:   1978TSA821

Reaction:   n-C4H10·C2H5 + ·C2H5
Reaction order:   1
Temperature:   300 - 1100 K
Pressure:  0.67 - 1.60 bar
Rate expression:   1.58x1017 [s-1] e-364174 [J/mole]/RT
Bath gas:   Ar
Category:  Review
Data type:   Experimental value and limited review

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
300 6.19E-47
350 7.08E-38
400 4.40E-31
450 8.46E-26
500 1.43E-21
550 4.10E-18
600 3.13E-15
650 8.59E-13
700 1.06E-10
750 6.85E-9
800 2.64E-7
850 6.60E-6
900 1.16E-4
950 1.50E-3
1000 1.50E-2
1050 1.21E-1
1100 8.05E-1