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Accessibility information
Author(s):   Clyne, M.A.A.; Holt, P.M.
Title:   Reaction Kinetics Involving Ground X2π and Excited A2Σ+ Hydroxyl Radicals. Part 1. - Quenching Kinetics of OH A2Σ+ and Rate Constants for Reactions of OH X2π with CH3CCl3 and CO
Journal:   J. Chem. Soc. Faraday Trans. 2
Volume:   75
Page(s):  
Year:   1979
Reference type:   Journal article
Squib:   1979CLY/HOL569

Reaction:   CO + ·OHCO2 +
Reaction order:   2
Temperature:   293 - 430 K
Pressure:  2.00E-3 - 2.60E-3 bar
Rate expression:   2.19x10-13 [cm3/molecule s] e-732 [±329 J/mole]/RT
Uncertainty:   1.3200001
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Electron beam
Analytical technique:   Resonance fluorescence

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
293 1.62E-13
300 1.63E-13
325 1.67E-13
350 1.70E-13
375 1.73E-13
400 1.76E-13
425 1.78E-13
430 1.79E-13