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Title: Temperature-dependent A factor in thermal unimolecular reactions
Journal: J. Phys. Chem.
Volume: 83
Page(s): 100 - 108
Year: 1979
Reference type: Journal article
Squib: 1979FOR100-108
Reaction:
n-C4H10 → ·C2H5 + ·C2H5
Reaction order:
1
Temperature:
1000 - 1200
K
Rate expression:
4.41x1018 [s-1] (T/298 K)-2.17 e-365005 [J/mole]/RT
Category: Theory
Data type:
Transition state theory
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 1000 | 2.74E-2 |
| 1025 | 7.58E-2 |
| 1050 | 1.99E-1 |
| 1075 | 5.01E-1 |
| 1100 | 1.21E0 |
| 1125 | 2.79E0 |
| 1150 | 6.21E0 |
| 1175 | 1.34E1 |
| 1200 | 2.78E1 |