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Title: Generalized transition state theory. Canonical variational calculations using the bond energy-bond order method for bimolecular reactions of combustion products
Journal: J. Am. Chem. Soc.
Volume: 101
Page(s):
Year: 1979
Reference type: Journal article
Squib: 1979GAR/TRU5207
Reaction:
Br· + BrCl → Br2 + Cl
Reaction order:
2
Temperature:
300 - 1000
K
Rate expression:
6.13x10-10 [cm3/molecule s] e-25775 [J/mole]/RT
Category: Theory
Data type:
Bond energy-bond order (BEBO)
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 300 | 1.99E-14 |
| 350 | 8.72E-14 |
| 400 | 2.64E-13 |
| 450 | 6.24E-13 |
| 500 | 1.24E-12 |
| 550 | 2.18E-12 |
| 600 | 3.49E-12 |
| 650 | 5.20E-12 |
| 700 | 7.31E-12 |
| 750 | 9.82E-12 |
| 800 | 1.27E-11 |
| 850 | 1.60E-11 |
| 900 | 1.96E-11 |
| 950 | 2.34E-11 |
| 1000 | 2.76E-11 |