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Accessibility information
Author(s):   King, K.D.; Gaynor, B.J.; Gilbert, R.G.
Title:   Competitive unimolecular reactions at low pressures. The pyrolysis of cyclobutyl chloride
Journal:   Int. J. Chem. Kinet.
Volume:   11
Page(s):   11 - 21
Year:   1979
Reference type:   Journal article
Squib:   1979KIN/GAY11-21

Reaction:   cyclobutyl chloride → 1,3-Butadiene + HCl
Reaction order:   1
Temperature:   892 - 1150 K
Rate expression:   3.98x1013 [s-1] e-232805 [±4664 J/mole]/RT
Uncertainty:   2.0
Bath gas:   cyclobutyl chloride
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
892 9.28E-1
900 1.23E0
925 2.84E0
950 6.30E0
975 1.34E1
1000 2.75E1
1025 5.45E1
1050 1.04E2
1075 1.94E2
1100 3.51E2
1125 6.18E2
1150 1.06E3