Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Feedback

Rate Our Products and Services

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Newman, C.G.; O'Neal, H.E.; Ring, M.A.; Leska, F.; Shipley, N.
Title:   Kinetics and mechanism of the silane decomposition
Journal:   Int. J. Chem. Kinet.
Volume:   11
Page(s):  
Year:   1979
Reference type:   Journal article
Squib:   1979NEW/ONE1167

Reaction:   CyclohexeneC2H4 + 1,3-Butadiene
Reaction order:   1
Reference reaction:   CyclopropaneCH3CH=CH2
Temperature:   1020 - 1200 K
Pressure:  5.20 - 5.33 bar
Rate expression:   1.82x1015 [s-1] e-274378 [±13719 J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1020 1.62E1
1025 1.90E1
1050 4.08E1
1075 8.48E1
1100 1.70E2
1125 3.32E2
1150 6.28E2
1175 1.16E3
1200 2.07E3