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Title: Pyrolysis of triethylgallium by the toluene carrier technique
Journal: Can. J. Chem.
Volume: 57
Page(s): 3178 - 3181
Year: 1979
Reference type: Journal article
Squib: 1979PAP/PRI3178-3181
Reaction:
Toluene + ·C2H5 → C2H6 + Benzyl
Reaction order:
2
Temperature:
464 - 701
K
Pressure: 8.20E-3 - 3.73E-2 bar
Rate expression:
1.99x10-13 [cm3/molecule s] e-40242 [±4822 J/mole]/RT
Bath gas:
Toluene
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 464 | 5.88E-18 |
| 475 | 7.49E-18 |
| 500 | 1.25E-17 |
| 525 | 1.98E-17 |
| 550 | 3.00E-17 |
| 575 | 4.40E-17 |
| 600 | 6.25E-17 |
| 625 | 8.63E-17 |
| 650 | 1.16E-16 |
| 675 | 1.53E-16 |
| 700 | 1.98E-16 |
| 701 | 2.00E-16 |