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Title: The absolute rate constant for the metathesis t-C4H9. + DI → C4H9D + I. and the heat of formation of the t-butyl radical
Journal: Int. J. Chem. Kinet.
Volume: 11
Page(s):
Year: 1979
Reference type: Journal article
Squib: 1979ROS/GOL969
Reaction:
tert-C4H9 + DI → (CH3)3CD + I
Reaction order:
2
Temperature:
644 - 722
K
Rate expression:
7.95x10-12 [cm3/molecule s] e-8896 [J/mole]/RT
Bath gas:
(tert-C4H9N)2
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Mass spectrometry
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 644 | 1.51E-12 |
| 650 | 1.53E-12 |
| 675 | 1.63E-12 |
| 700 | 1.72E-12 |
| 722 | 1.81E-12 |