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Accessibility information
Author(s):   Gammie, L.; Safarik, I.; Strausz, O.P.; Roberge, R.; Sandorfy, C.
Title:   Disproportionation and hydrogen abstraction reactions of trimethylsilyl radicals
Journal:   J. Am. Chem. Soc.
Volume:   102
Page(s):  
Year:   1980
Reference type:   Journal article
Squib:   1980GAM/SAF378

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1980GAM/SAF378   iso-C4H10 + (CH3)3Si· → (CH3)3SiH + tert-C4H9  298   4.23E-20           4.23E-20  2
  1980GAM/SAF378   CH3SiH3 + (CH3)3Si· → (CH3)3SiH + CH3SiH2  298   3.24E-18           3.24E-18  2
  1980GAM/SAF378   (CH3)2SiD2 + (CH3)3Si· → Other Products + (CH3)3SiD  298   4.23E-19           4.23E-19  2
  1980GAM/SAF378   CH3SiD3 + (CH3)3Si· → Other Products + (CH3)3SiD  298   9.48E-19           9.48E-19  2
  1980GAM/SAF378   (CH3)2SiH2 + (CH3)3Si· → (CH3)3SiH + (CH3)2SiH  298   7.85E-19           7.85E-19  2
  1980GAM/SAF378   Si2H6 + (CH3)3Si· → (CH3)3SiH + Si2H5  298   5.40E-16           5.40E-16  2
  1980GAM/SAF378   SiH4 + (CH3)3Si· → (CH3)3SiH + SiH3  298   1.08E-17           1.08E-17  2
  1980GAM/SAF378   SiD4 + (CH3)3Si· → (CH3)3SiD + SiD3  298   1.55E-18           1.55E-18  2
  1980GAM/SAF378   Si2D6 + (CH3)3Si· → Other Products + (CH3)3SiD  298   9.25E-17           9.25E-17  2
  1980GAM/SAF378   SiH3 + (CH3)3Si· → (CH3)3SiH + SiH2  298   0.80           0.80  2
  Reference reaction:  SiH3 + (CH3)3Si· → (CH3)3SiSiH3 2
  1980GAM/SAF378   (CH3)3Si· + (CH3)3Si· → (CH3)3SiH + (CH3)2Si=CH2  298   0.50           0.50  2
  Reference reaction:  (CH3)3Si· + (CH3)3Si· → (CH3)6Si2 2
  1980GAM/SAF378   (CH3)3Si· + CH3SiH2 → Other Products + (CH3)3SiH  298   0.50           0.50  2
  Reference reaction:  (CH3)3Si· + CH3SiH2 → (CH3)3SiSiH2CH3 2
  1980GAM/SAF378   (CH3)3Si· + (CH3)2SiH → (CH3)3SiH + CH2=SiHCH3  298   0.30           0.30  2
  Reference reaction:  (CH3)3Si· + (CH3)2SiH → (CH3)3SiSiH(CH3)2 2
Search returned 13 records.