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Accessibility information
Author(s):   Gilbert, R.G.; King, K.D.
Title:   Gas/gas and gas/wall average energy transfer from very low-pressure pyrolysis
Journal:   Chem. Phys.
Volume:   49
Page(s):   367 - 375
Year:   1980
Reference type:   Journal article
Squib:   1980GIL/KIN367-375

Reaction:   cyclobutyl chloride → 1,3-Butadiene + HCl
Reaction order:   1
Temperature:   800 - 1200 K
Rate expression:   3.98x1013 [s-1] e-231974 [J/mole]/RT
Bath gas:   cyclobutyl chloride
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
800 2.84E-2
825 8.18E-2
850 2.21E-1
875 5.65E-1
900 1.37E0
925 3.17E0
950 7.00E0
975 1.49E1
1000 3.04E1
1025 6.01E1
1050 1.15E2
1075 2.13E2
1100 3.84E2
1125 6.75E2
1150 1.16E3
1175 1.94E3
1200 3.18E3