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Accessibility information
Author(s):   Astholz, D.C.; Durant, J.; Troe, J.
Title:   Theraml decomposition of toluene and of benzyl radicals in shock waves
Journal:   Symp. Int. Combust. Proc.
Volume:   18
Page(s):  
Year:   1981
Reference type:   Journal article
Squib:   1981AST/DUR885

Reaction:   TolueneBenzyl +
Reaction order:   1
Temperature:   1100 - 1800 K
Pressure:  0.20 - 4.96 bar
Rate expression:   8.0x1016 [s-1] e-379971 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1100 7.25E-2
1150 4.41E-1
1200 2.31E0
1250 1.06E1
1300 4.32E1
1350 1.59E2
1400 5.33E2
1450 1.64E3
1500 4.69E3
1550 1.25E4
1600 3.15E4
1650 7.49E4
1700 1.69E5
1750 3.65E5
1800 7.53E5