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Title: Evaluated kinetic data for high temperature reactions. Volume 4 Homogeneous gas phase reactions of halogen- and cyanide- containing species
Journal: J. Phys. Chem. Ref. Data
Volume: 10
Year: 1981
Reference type: Journal article
Squib: 1981BAU/DUX
Reaction:
CH3CCl3 + ·OH → H2O + CCl3CH2
Reaction order:
2
Temperature:
260 - 400
K
Rate expression:
3.5x10-12 [cm3/molecule s] e-12971 [J/mole]/RT
Uncertainty:
1.3
Category: Review
Data type:
Extensive literature review
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 260 | 8.68E-15 |
| 275 | 1.20E-14 |
| 300 | 1.93E-14 |
| 325 | 2.88E-14 |
| 350 | 4.06E-14 |
| 375 | 5.47E-14 |
| 400 | 7.09E-14 |