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Accessibility information
Author(s):   Choo, K.Y.; Benson, S.W.
Title:   Arrhenius Parameters for the Alkoxy Radical Decomposition Reactions
Journal:   Int. J. Chem. Kinet.
Volume:   13
Page(s):  
Year:   1981
Reference type:   Journal article
Squib:   1981CHO/BEN833

Reaction:   (CH3)3CO → (CH3)2CO + ·CH3
Reaction order:   1
Temperature:   298 - 450 K
Rate expression:   1.26x1014 [s-1] e-64021 [J/mole]/RT
Category:  Theory
Data type:   Other theoretical

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
298 7.56E2
300 8.98E2
325 6.47E3
350 3.51E4
375 1.52E5
400 5.50E5
425 1.71E6
450 4.67E6