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Accessibility information
Author(s):   Choo, K.Y.; Benson, S.W.
Title:   Arrhenius Parameters for the Alkoxy Radical Decomposition Reactions
Journal:   Int. J. Chem. Kinet.
Volume:   13
Page(s):  
Year:   1981
Reference type:   Journal article
Squib:   1981CHO/BEN833

Reaction:   (CH3)2CHC(O)(CH3)2 → (CH3)2CO + iso-C3H7
Reaction order:   1
Temperature:   298 - 450 K
Rate expression:   3.98x1013 [s-1] e-40575 [J/mole]/RT
Category:  Theory
Data type:   Other theoretical

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
298 3.08E6
300 3.43E6
325 1.20E7
350 3.50E7
375 8.88E7
400 2.00E8
425 4.10E8
450 7.77E8