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Title: Kinetics and mechanism of the thermal decomposition of cyclopentyl cyanide
Journal: Int. J. Chem. Kinet.
Volume: 13
Page(s):
Year: 1981
Reference type: Journal article
Squib: 1981KIN/GOD755
Reaction:
Cyclopentanecarbonitrile → CH2CHCN + CH3CH=CH2
Reaction order:
1
Temperature:
905 - 1140
K
Rate expression:
1.0x1016 [s-1] e-335073 [±3351 J/mole]/RT
Uncertainty:
2.0
Bath gas:
N2
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 905 | 4.58E-4 |
| 925 | 1.20E-3 |
| 950 | 3.77E-3 |
| 975 | 1.12E-2 |
| 1000 | 3.15E-2 |
| 1025 | 8.41E-2 |
| 1050 | 2.14E-1 |
| 1075 | 5.24E-1 |
| 1100 | 1.23E0 |
| 1125 | 2.77E0 |
| 1140 | 4.44E0 |