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Accessibility information
Author(s):   Koike, T.; Morinaga, K.
Title:   UV Absorption Studies of the Pyrolysis of Butane in Shock Waves
Journal:   Bull. Chem. Soc. Jpn.
Volume:   54
Page(s):  
Year:   1981
Reference type:   Journal article
Squib:   1981KOI/MOR2439

Reaction:   n-C4H10n-C3H7 + ·CH3
Reaction order:   1
Temperature:   1290 - 1610 K
Pressure:  2.67E-2 bar
Rate expression:   8.89x1013 [s-1] e-300984 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1290 5.78E1
1300 7.17E1
1325 1.21E2
1350 2.01E2
1375 3.27E2
1400 5.24E2
1425 8.25E2
1450 1.28E3
1475 1.95E3
1500 2.94E3
1525 4.36E3
1550 6.40E3
1575 9.27E3
1600 1.33E4
1610 1.53E4