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Accessibility information
Author(s):   Skinner, G.B.; Rogers, D.; Patel, K.B.
Title:   Consistency of theory and experiment in the ethane-methyl radical system
Journal:   Int. J. Chem. Kinet.
Volume:   13
Page(s):  
Year:   1981
Reference type:   Journal article
Squib:   1981SKI/ROG481

Reaction:   CyclohexeneC2H4 + 1,3-Butadiene
Reaction order:   1
Temperature:   1000 - 1340 K
Pressure:  3.04 - 9.12 bar
Rate expression:   2.51x1015 [s-1] e-280198 [±11225 J/mole]/RT
Uncertainty:   3.1600001
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1000 5.81E0
1025 1.32E1
1050 2.89E1
1075 6.10E1
1100 1.24E2
1125 2.46E2
1150 4.71E2
1175 8.78E2
1200 1.60E3
1225 2.83E3
1250 4.91E3
1275 8.33E3
1300 1.38E4
1325 2.26E4
1340 3.00E4