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Accessibility information
Author(s):   Tsuboi, T.; Hashimoto, K.
Title:   Shock Tube Study on Homogeneous Thermal Oxidation of Methanol
Journal:   Combust. Flame
Volume:   42
Year:   1981
Reference type:   Journal article
Squib:   1981TSU/HAS61

Reaction:   CH3OH + ·OH(·)CH2OH + H2O
Reaction order:   2
Temperature:   1200 - 1800 K
Pressure:  0.20 - 5.07 bar
Rate expression:   3.32x10-10 [cm3/molecule s] e-25027 [J/mole]/RT
Bath gas:   Ar
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
1200 2.70E-11
1250 2.99E-11
1300 3.28E-11
1350 3.57E-11
1400 3.87E-11
1450 4.17E-11
1500 4.46E-11
1550 4.76E-11
1600 5.06E-11
1650 5.36E-11
1700 5.65E-11
1750 5.95E-11
1800 6.24E-11