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Accessibility information
Author(s):   Tsuboi, T.; Katoh, M.; Kikuchi, S.; Hashimoto, K.
Title:   Thermal Decomposition of Methanol behind Shock Waves
Journal:   Jpn. J. Appl. Phys.
Volume:   20
Page(s):  
Year:   1981
Reference type:   Journal article
Squib:   1981TSU/KAT985

Reaction:   CH3OH·CH3 + ·OH
Reaction order:   1
Temperature:   1500 - 1900 K
Pressure:  9.33E-3 bar
Rate expression:   2.0x1018 [s-1] e-394937 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1500 3.53E4
1525 5.94E4
1550 9.82E4
1575 1.60E5
1600 2.56E5
1625 4.04E5
1650 6.29E5
1675 9.67E5
1700 1.47E6
1725 2.20E6
1750 3.26E6
1775 4.78E6
1800 6.93E6
1825 9.94E6
1850 1.41E7
1875 1.99E7
1900 2.78E7