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Author(s):   Ashmore, P.G.; Owen, A.J.; Robinson, P.J.
Title:   Chlorine-catalysed pyrolysis of 1,2-dichloroethane. Part 2.-Unimolecular decomposition of the 1,2-dichloroethyl radical and its reverse reaction
Journal:   J. Chem. Soc. Perkin Trans. 1
Volume:   78
Page(s):   677 - 693
Year:   1982
Reference type:   Journal article
Squib:   1982ASH/OWE677-693

Reaction:   CH2=CHCl + Cl → CH2ClCHCl·
Reaction order:   2
Temperature:   520 - 595 K
Pressure:  1.33E-2 - 0.13 bar
Rate expression:   3.02x10-9 [cm3/molecule s] e-16712 [J/mole]/RT
Bath gas:   Unknown
Category:  Experiment
Data type:   RRK(M) extrapolation

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
520 6.33E-11
525 6.57E-11
550 7.82E-11
575 9.17E-11
595 1.03E-10