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Accessibility information
Author(s):   Astholz, D.C.; Troe, J.
Title:   Thermal decomposition of benzyl radicals in shock waves
Journal:   J. Chem. Soc. Faraday Trans. 2
Volume:   78
Page(s):  
Year:   1982
Reference type:   Journal article
Squib:   1982AST/TRO1413

Reaction:   Toluene → Products
Reaction order:   1
Temperature:   1550 - 2030 K
Pressure:  0.10 - 3.75 bar
Rate expression:   8.3x1017 [s-1] e-454802 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1550 3.91E2
1575 6.85E2
1600 1.18E3
1625 2.00E3
1650 3.32E3
1675 5.45E3
1700 8.81E3
1725 1.40E4
1750 2.21E4
1775 3.43E4
1800 5.26E4
1825 7.98E4
1850 1.20E5
1875 1.78E5
1900 2.61E5
1925 3.79E5
1950 5.45E5
1975 7.78E5
2000 1.10E6
2025 1.54E6
2030 1.65E6