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Author(s):   Baldwin, R.R.; Hisham, M.W.M.; Walker, R.W.
Title:   Arrhenius parameters of elementary reactions involved in the oxidation of neopentane
Journal:   J. Chem. Soc. Faraday Trans. 1
Volume:   78
Page(s):  
Year:   1982
Reference type:   Journal article
Squib:   1982BAL/HIS1615

Reaction:   (CH3)2C(CH2OOH)CH2· → Other Products + (CH3)2CO
Reaction order:   1
Temperature:   653 - 793 K
Pressure:  0.67 bar
Rate expression:   1.25x1012 [s-1] e-96448 [J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
653 2.41E4
675 4.30E4
700 7.94E4
725 1.41E5
750 2.40E5
775 3.95E5
793 5.55E5