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Title: Decomposition of the t-butoxy radical
Journal: Phys. Chem. Behav. Atmos. Pollut. Proc. Eur. Symp.
Page(s):
Year: 1982
Reference type: Journal article
Squib: 1982BAT/ROB172
Reaction:
(CH3)3CO → (CH3)2CO + ·CH3
Reaction order:
1
Temperature:
402 - 443
K
Pressure: 3.33E-2 - 2.00 bar
Rate expression:
7.94x1014 [s-1] e-69426 [J/mole]/RT
Bath gas:
Ar
Category: Experiment
Data type:
RRK(M) extrapolation
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 402 | 7.57E5 |
| 425 | 2.33E6 |
| 443 | 5.17E6 |