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Accessibility information
Author(s):   Black, G.; Sharpless, R.L.; Slanger, T.G.
Title:   Rate Coefficient s for SO Reactions with O2 and O3 over the Temperature Range 230 to 420 K
Journal:   Chem. Phys. Lett.
Volume:   93
Year:   1982
Reference type:   Journal article
Squib:   1982BLA/SHA598

Reaction:   O2 + SOSO2 +
Reaction order:   2
Temperature:   230 - 420 K
Pressure:  0.53 bar
Rate expression:   2.41x10-13 [±1.99x10-13 cm3/molecule s] e-19705 [±2170 J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Chemiluminescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
230 8.06E-18
250 1.84E-17
275 4.35E-17
300 8.93E-17
325 1.64E-16
350 2.76E-16
375 4.33E-16
400 6.43E-16
420 8.53E-16