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Author(s):   Dai, H-L.; Specht, E.; Berman, M.R.
Title:   Determination of arrhenius parameters for unimolecular reactions of chloroalkanes by IR laser pyrolysis
Journal:   J. Chem. Phys.
Volume:   77
Page(s):   4494 - 4506
Year:   1982
Reference type:   Journal article
Squib:   1982DAI/SPE4494-4506

Associated entries:

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Rate expression: k(T) = A (T/298 K)ⁿ e^-Ea/RT
Rate expression units:
First order: s^-1
Second order: cm³/molecule s
Third order: cm⁶/molecule² s
R = 8.314472 J / mole K

Energy Units	J	Molecular Units	Molecule
Pressure Units	bar	Temperature Units	K
Base Volume Unit	cm	Reference Temperature	298.0
Evaluation Temperature	298.0

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Squib	Reaction	Temp [K]	A	Ea [J/mole]	Order
1982DAI/SPE4494-4506	CH₃CCl₃ → CH₂=CCl₂ + HCl	1130 - 1350	1.26E13	2.07E05	1
1982DAI/SPE4494-4506	C₂H₅Cl → C₂H₄ + HCl	1100 - 1400	6.31E13	2.40E05	1
1982DAI/SPE4494-4506	CHCl₂CH₂Cl → (Z)-CHCl=CHCl + HCl	1150 - 1400	1.26E14	2.44E05	1
1982DAI/SPE4494-4506	CHCl₂CH₂Cl → (E)-CHCl=CHCl + HCl	1150 - 1400	7.94E13	2.49E05	1

Search returned 4 records.