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Accessibility information
Author(s):   Dai, H-L.; Specht, E.; Berman, M.R.
Title:   Determination of arrhenius parameters for unimolecular reactions of chloroalkanes by IR laser pyrolysis
Journal:   J. Chem. Phys.
Volume:   77
Page(s):   4494 - 4506
Year:   1982
Reference type:   Journal article
Squib:   1982DAI/SPE4494-4506

Reaction:   CH3CCl3CH2=CCl2 + HCl
Reaction order:   1
Temperature:   1130 - 1350 K
Pressure:  6.53E-3 bar
Rate expression:   1.26x1013 [s-1] e-207030 [±6211 J/mole]/RT
Uncertainty:   2.0
Bath gas:   SiF4
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1130 3.39E3
1150 4.98E3
1175 7.89E3
1200 1.23E4
1225 1.87E4
1250 2.81E4
1275 4.16E4
1300 6.05E4
1325 8.69E4
1350 1.23E5