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Accessibility information
Author(s):   Dai, H-L.; Specht, E.; Berman, M.R.
Title:   Determination of arrhenius parameters for unimolecular reactions of chloroalkanes by IR laser pyrolysis
Journal:   J. Chem. Phys.
Volume:   77
Page(s):   4494 - 4506
Year:   1982
Reference type:   Journal article
Squib:   1982DAI/SPE4494-4506

Reaction:   CHCl2CH2Cl(Z)-CHCl=CHCl + HCl
Reaction order:   1
Temperature:   1150 - 1400 K
Pressure:  6.53E-3 bar
Rate expression:   1.26x1014 [s-1] e-244445 [±7342 J/mole]/RT
Uncertainty:   2.51
Bath gas:   SiF4
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1150 9.94E2
1175 1.71E3
1200 2.89E3
1225 4.76E3
1250 7.69E3
1275 1.22E4
1300 1.90E4
1325 2.91E4
1350 4.39E4
1375 6.52E4
1400 9.55E4