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Title: Determination of arrhenius parameters for unimolecular reactions of chloroalkanes by IR laser pyrolysis
Journal: J. Chem. Phys.
Volume: 77
Page(s): 4494 - 4506
Year: 1982
Reference type: Journal article
Squib: 1982DAI/SPE4494-4506
Reaction:
CHCl2CH2Cl → (Z)-CHCl=CHCl + HCl
Reaction order:
1
Temperature:
1150 - 1400
K
Pressure: 6.53E-3 bar
Rate expression:
1.26x1014 [s-1] e-244445 [±7342 J/mole]/RT
Uncertainty:
2.51
Bath gas:
SiF4
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 1150 | 9.94E2 |
| 1175 | 1.71E3 |
| 1200 | 2.89E3 |
| 1225 | 4.76E3 |
| 1250 | 7.69E3 |
| 1275 | 1.22E4 |
| 1300 | 1.90E4 |
| 1325 | 2.91E4 |
| 1350 | 4.39E4 |
| 1375 | 6.52E4 |
| 1400 | 9.55E4 |