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Accessibility information
Author(s):   Dai, H-L.; Specht, E.; Berman, M.R.
Title:   Determination of arrhenius parameters for unimolecular reactions of chloroalkanes by IR laser pyrolysis
Journal:   J. Chem. Phys.
Volume:   77
Page(s):   4494 - 4506
Year:   1982
Reference type:   Journal article
Squib:   1982DAI/SPE4494-4506

Reaction:   CHCl2CH2Cl(E)-CHCl=CHCl + HCl
Reaction order:   1
Temperature:   1150 - 1400 K
Pressure:  6.53E-3 bar
Rate expression:   7.94x1013 [s-1] e-248603 [±7466 J/mole]/RT
Uncertainty:   2.51
Bath gas:   SiF4
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1150 4.06E2
1175 7.05E2
1200 1.20E3
1225 1.99E3
1250 3.25E3
1275 5.19E3
1300 8.15E3
1325 1.26E4
1350 1.91E4
1375 2.86E4
1400 4.21E4