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Accessibility information
Author(s):   Eaborn, C.; Mahmoud, F.M.S.; Taylor, R.
Title:   The mechanism of the gas-phase pyrolysis of esters. Part 13. The very strong activating effects of β-trialkylmetal groups
Journal:   J. Chem. Soc. Perkin Trans. 2
Page(s):   1313 - 1319
Year:   1982
Reference type:   Journal article
Squib:   1982EAB/MAH1313-1319

Reaction:   CH3COOC2H5CH3C(O)OH + C2H4
Reaction order:   1
Temperature:   638 - 696 K
Rate expression:   3.13x1012 [s-1] e-202873 [J/mole]/RT
Bath gas:   CH3COOC2H5
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Other (direct)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
638 7.69E-5
650 1.56E-4
675 6.26E-4
696 1.86E-3