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Title: The mechanism of the gas-phase pyrolysis of esters. Part 13. The very strong activating effects of β-trialkylmetal groups
Journal: J. Chem. Soc. Perkin Trans. 2
Page(s): 1313 - 1319
Year: 1982
Reference type: Journal article
Squib: 1982EAB/MAH1313-1319
Reaction:
CH3COOC2H5 → CH3C(O)OH + C2H4
Reaction order:
1
Temperature:
638 - 696
K
Rate expression:
3.13x1012 [s-1] e-202873 [J/mole]/RT
Bath gas:
CH3COOC2H5
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Other (direct)
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 638 | 7.69E-5 |
| 650 | 1.56E-4 |
| 675 | 6.26E-4 |
| 696 | 1.86E-3 |