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Accessibility information
Author(s):   Failes, R.L.; Singleton, D.L.; Paraskevopoulos, G.; Irwin, R.S.
Title:   Rate Constants for the Reaction of Ground-State Oxygen Atoms with Methanol from 297 to 544 K
Journal:   Int. J. Chem. Kinet.
Volume:   14
Year:   1982
Reference type:   Journal article
Squib:   1982FAI/SIN371

Reaction:   CH3OH + (·)CH2OH + ·OH
Reaction order:   2
Temperature:   297 - 544 K
Pressure:  3.63E-2 - 6.12E-2 bar
Rate expression:   1.63x10-11 [±4.48x10-12 cm3/molecule s] e-18874 [±940 J/mole]/RT
Bath gas:   N2O
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Sensitized photolysis
Analytical technique:   Chemiluminescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
297 7.79E-15
300 8.41E-15
325 1.51E-14
350 2.48E-14
375 3.82E-14
400 5.58E-14
425 7.79E-14
450 1.05E-13
475 1.37E-13
500 1.74E-13
525 2.15E-13
544 2.51E-13