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Title: Rate Constants for the Reaction of Ground-State Oxygen Atoms with Methanol from 297 to 544 K
Journal: Int. J. Chem. Kinet.
Volume: 14
Page(s):
Year: 1982
Reference type: Journal article
Squib: 1982FAI/SIN371
Reaction:
CH3OH + O· → (·)CH2OH + ·OH
Reaction order:
2
Temperature:
297 - 544
K
Pressure: 3.63E-2 - 6.12E-2 bar
Rate expression:
1.63x10-11 [±4.48x10-12 cm3/molecule s] e-18874 [±940 J/mole]/RT
Bath gas:
N2O
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Sensitized photolysis
Analytical technique:
Chemiluminescence
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 297 | 7.79E-15 |
| 300 | 8.41E-15 |
| 325 | 1.51E-14 |
| 350 | 2.48E-14 |
| 375 | 3.82E-14 |
| 400 | 5.58E-14 |
| 425 | 7.79E-14 |
| 450 | 1.05E-13 |
| 475 | 1.37E-13 |
| 500 | 1.74E-13 |
| 525 | 2.15E-13 |
| 544 | 2.51E-13 |