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Title: Kinetics of the Thermal Reactions of Bicyclo[4.2.2]deca-3,7-diene and endo- and exo-5-Vinylbicyclo[2.2.2]oct-2-ene in the Gas Phase
Journal: Int. J. Chem. Kinet.
Volume: 14
Page(s):
Year: 1982
Reference type: Journal article
Squib: 1982HUY/HUB251
Reaction:
Bicyclo[2.2.2]oct-2-ene, 5-ethenyl-,(1α,4α,5α)- → 1,3-Butadiene + 1,3-Cyclohexadiene
Reaction order:
1
Temperature:
513 - 578
K
Pressure: 2.67E-3 - 5.33E-2 bar
Rate expression:
8.91x1014 [s-1] e-221996 [J/mole]/RT
Uncertainty:
1.1
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 513 | 2.22E-8 |
| 525 | 7.29E-8 |
| 550 | 7.36E-7 |
| 575 | 6.07E-6 |
| 578 | 7.73E-6 |