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Accessibility information
Author(s):   Jeong, K-M.; Kaufman, F.
Title:   Kinetics of the Reaction of Hydroxyl Radical with Methane and with Nine Cl- and F-Substituted Methanes. 1. Experimental Results, Comparisons, and Applications
Journal:   J. Phys. Chem.
Volume:   86
Year:   1982
Reference type:   Journal article
Squib:   1982JEO/KAU1808

Reaction:   CH2Cl2 + ·OHCHCl2 + H2O
Reaction order:   2
Temperature:   251 - 455 K
Pressure:  4.00E-3 bar
Rate expression:   5.73x10-12 [±7.47x10-13 cm3/molecule s] e-8730 [±348 J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Electron beam
Analytical technique:   Resonance fluorescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
251 8.74E-14
275 1.26E-13
300 1.73E-13
325 2.26E-13
350 2.85E-13
375 3.48E-13
400 4.15E-13
425 4.84E-13
450 5.56E-13
455 5.70E-13