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Title: Recalculation of the kinetic constants for the oxidation of alkaline-earth metal vapours
Journal: Russ. J. Phys. Chem. (Engl. Transl.)
Volume: 56
Page(s): 630 - 631
Year: 1982
Reference type: Journal article
Squib: 1982KAS/MAN630-631
Reaction:
Mg + Br2 → Br· + Magnesium bromide
Reaction order:
2
Temperature:
873 - 1020
K
Rate expression:
9.15x10-10 [±2.82x10-11 cm3/molecule s] (T/298 K)-4.50
Bath gas:
Ar
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Other (direct)
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 873 | 7.26E-12 |
| 875 | 7.18E-12 |
| 900 | 6.33E-12 |
| 925 | 5.59E-12 |
| 950 | 4.96E-12 |
| 975 | 4.41E-12 |
| 1000 | 3.94E-12 |
| 1020 | 3.60E-12 |